A visible-light-promoted radical reaction system for azidation and halogenation of tertiary aliphatic C-H bonds.

A visible-light-promoted radical reaction system for azidation and halogenation of tertiary aliphatic C–H bonds† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c5sc04169d Click here for additional data file.

Manganese-catalyzed late-stage aliphatic C-H azidation.

We report a manganese-catalyzed aliphatic C-H azidation reaction that can efficiently convert secondary, tertiary, and benzylic C-H bonds to the corresponding azides. The method utilizes aqueous sodium azide solution as the azide source and can be performed under air. Besides its operational simplicity, the potential of this method for late-stage functionalization has been demonstrated by succe...

Benzylic C-H Azidation Using the Zhdankin Reagent and a Copper Photoredox Catalyst.

An azidation method for C-N bond formation at benzylic C-H positions is described using copper-catalyzed visible light photochemistry and the Zhdankin azidoiodinane reagent. The method is applicable to a wide range of substrates bearing different functional groups and having a primary, secondary, or tertiary benzylic position, and is thought to proceed through a radical chain reaction.

Direct nitration and azidation of aliphatic carbons by an iron-dependent halogenase

Iron-dependent halogenases employ cis-halo-Fe(IV)-oxo (haloferryl) complexes to functionalize unactivated aliphatic carbon centers, a capability elusive to synthetic chemists. Halogenation requires (i) coordination of a halide anion (Cl(-) or Br(-)) to the enzyme's Fe(II) cofactor, (ii) coupled activation of O2 and decarboxylation of α-ketoglutarate to generate the haloferryl intermediate, (iii...

بررسی میزان پلیمریزاسیون یک رزین باندینگ آزمایشگاهی کیور شده باLED  توسط دستگاه DSC

Background and Aim: Extent of polymerization (Ep) is the rate at which methacrylate C=C bonds are converted to aliphatic C-C bonds. The higher the Ep value, the better the polymerization of the polymer. If the polymer dose not polymerize sufficiently, it could have destructive effects e.g. releasing monomer, initiator, free radical or insufficient polymerization of hybrid layer. Therefore, meas...